2020年诺贝尔化学奖的再思考——归属争议与原创表彰

2020年诺贝尔化学奖授予两位女性科学家——埃马纽埃尔.卡彭蒂耶和詹妮弗.杜德纳。回顾CRISPR-Cas9技术的发展史,她们完整地说明了该技术的原理、作用,并研发了CRISPR-Cas9基因编辑技术,符合诺贝尔奖奖励原创的要求,是争议最小的获奖者人选。专利和诺贝尔奖在维护发明者权益、促进科学的发展上都具有重要的作用,且不能仅以其中一项的结果判断另一项的归属,目前的归属差异不影响非商业应用的学术研究,并客观上推动了原创研究的产出。进一步思考原创的概念,明确基础科学的定位,加强对创新人才的鼓励和支持,注重诺贝尔奖颁奖历史的梳理,也是本次诺贝尔奖给予我们的启示。     

锰氧化物中氧空位的构建及其催化氧化苯系物作用机制研究进展

作为一种过渡金属氧化物,锰氧化物以其多晶型、储/释氧能力强、蕴含丰富氧物种、结构缺陷可控等优点被广泛应用于苯系物的热催化氧化。其中,具有众多特性的氧空位能有效促进苯系物的完全催化氧化,因而成为各界研究的焦点。我们综述了常见的氧空位构建方法及表征技术,并总结了在苯系物催化氧化过程中,锰氧化物中氧空位的几种重要作用机制对催化活性和抗水性能的积极影响。最后文章对氧空位构建新方法、形成机理、具体过程及其在锰氧化物热催化氧化苯系物领域中的应用进行了总结和展望。     

点支承四边自由各向异性平行四边形板自由振动、屈曲和弯曲分析

一个精确的重富立叶级数解析解用于分析四边形自由的点支横观各向异性平行四边形板的自由振动、屈曲和弯曲。解析解用叠加法得到,此解收敛迅速。与现有结果的比较证实了由本法得到的解析解的精确性。文后用图表给出高精度的自由振动、屈曲和弯曲计算结果。     

Renewal of basic laws and principles for polar continuum theories （XI）——consistency problems

Some consistency problems existing in continuum field theories are briefly reviewed. Three arts of consistency problems are clarified based on the renewed basic laws for polar continua. The first art discusses the consistency problems between the basic laws for polar continua. The second art discusses the consistency problems between the basic laws for polar continua and for other nonpolar continua. The third art discusses the consistency problems between the basic laws for micropolar continuum theories and the dynamical equations for rigid body. The results presented here can help us to get a deeper understanding the structure of the basic laws for various continuum theories and the interrelations between them. In the meantime, these results obtained show clearly that the consistency problems could not be solved in the framework of traditional basic laws for continuum field theories.     

A STABILITY STUDY OF NAVIER-STOKES EQUATIONS (Ⅲ)

ＡＳＴＡＢＩＬＩＴＹＳＴＵＤＹＯＦＮＡＶＩＥＲ－ＳＴＯＫＥＳＥＱＵＡＴＩＯＮＳ（Ⅲ）ＳｈｉＷｅｉ－ｈｕｉ（施惟慧）（ｓｈａｎｇｈａｉＵｎｉｖｅｒｓｉｌｙ．Ｓｈａｎｇｈａｉ）（ＲｅｃｅｉｖｅｄＪａｎ．２０．１９９４；ＣｏｍｍｕｎｉｃａｔｅｄｂｙＣｈｉｅ...     

Diffuse mode bifurcation of soil causing convection-like shear investigated by group-theoretic image analysis

Diffuse mode bifurcation of soil under plane-strain compression test is shown, by means of an image analysis based on group-theoretic bifurcation theory, to trigger convection-like shear and to precede shear band formation. First digital photos of Toyoura sand specimens are processed by PIV (particle image velocimetry) to gather digitized images of deformation. Next bifurcation from a uniform state is detected by expanding these images into the double Fourier series and finding a predominant harmonic diffuse bifurcation mode based on that theory. This harmonic bifurcation mode, which is the mixture of a few harmonic functions, expresses complex convection-like shear. Last bifurcation from a non-uniform state is detected by decomposing each image into a few images with different symmetries to extract non-harmonic diffuse bifurcation modes. Diffuse modes of bifurcation, which hitherto were hidden behind predominant uniform compressive deformation, have thus been made transparent by virtue of the group-theoretic image analysis proposed. A possible course of deformation suggested herein is the evolution of diffuse mode bifurcation with a convection-like bifurcation mode breaking uniformity and symmetry, followed by the formation of shear bands through localization.     

Global structural behaviour of thin and moderately thick monoclinic spherical shells using a mixed shear deformation model

Summary The static and dynamic responses of anisotropic spherical shells under a uniformly distributed transverse load are investigated. Analytical solutions using the mixed variational formulation are presented for spherical shells subjected to various boundary conditions. Numerical results of a refined mixed first-order shear deformation theory for natural frequencies, critical buckling, center deflections and stresses are compared with those obtained using the classical shell theory. A variety of simply-supported and clamped boundary conditions are considered and comparisons with the existing literature are made. The sample numerical results presented herein for global structural behaviour of monoclinic spherical shells should serve as references for future comparisons.     

An Approximate Analytical Solution for Counter-Current Spontaneous Imbibition

An approximate analytical solution is provided for one-dimensional, counter- current, spontaneous imbibition of a wetting phase (water) into a semi-infinite porous medium. The solution is based on the assumption that a similarity solution exists for the displacement process. This assumption, in turn, rests on the assumption that the set of relative permeability and capillary pressures curves are unique functions of saturation and do not depend on the nature of the displacement. It further rests on the assumption that the saturation at the imbibition face does not vary with time. It is demonstrated that the solution is in agreement with results obtained from experiments and also numerical analyses of these experiments. The experiments utilize cylindrical samples with the radial surface and one end-face sealed, and with counter-current imbibition occurring at the open end-face. The stage of the experiment that is modeled by the present solution is the period before the imbibition front contacts the sealed end-face. An important finding of the present analysis is that the pressure upstream of the advancing invasion front is a constant. A second, improved solution is also presented; this solution is an iterative, series solution of an integral-differential equation. It converges to a stable solution in very few terms.     

Asymptotic Axially Symmetric Deformations for Perfectly Elastic Neo-Hookean and Mooney Materials

For axially symmetric deformations of the perfectly elastic neo-Hookean and Mooney materials, formal series solutions are determined in terms of expansions in appropriate powers of 1/R, where R is the cylindrical polar coordinate for the material coordinates. Remarkably, for both the neo-Hookean and Mooney materials, the first three terms of such expansions can be completely determined analytically in terms of elementary integrals. From the incompressibility condition and the equilibrium equations, the six unknown deformation functions, appearing in the first three terms can be reduced to five formal integrations involving in total seven arbitrary constants A, B, C, D, E, H and k ², and a further five integration constants, making a total of 12 integration constants for the deformation field. The solutions obtained for the neo-Hookean material are applied to the problem of the axial compression of a cylindrical rubber tube which has bonded metal end-plates. The solution so determined is approximate in two senses; namely as an approximate solution of the governing equations and for which the stress free and displacement boundary conditions are satisfied in an average manner only. The resulting load-deflection relation is shown graphically. The solution so determined, although approximate, attempts to solve a problem not previously tackled in the literature.      

Effective properties of elastic periodic composite media with fibers

A series solution to obtain the effective properties of some elastic composites media having periodically located heterogeneities is described. The method uses the classical expansion along Neuman series of the solution of the periodic elasticity problem in Fourier space, based on the Green's tensor, and exact expressions of factors depending on the shape of the inclusions. Some properties of convergence of the solution are presented, more specifically concerning the elasticity tensor of the reference medium, showing that the convergence occurs even for empty fibers. The solution is extended for rigid inclusions. A comparison is made with previous exact solutions for a fiber composite made of cylindrical fibers with circular cross-sections and with previous estimates. Different examples are presented for new situations concerning the study of fiber composites: composites with elliptic cross-sections and multi-phase fibrous composites.